[Group A] [Group B] [Group C] [Group D] [Group E] [Group F] [Group G] [Group H]
| Day | Date | Team 1 | Team 2 | Score |
| 1 | 2021-09-14 | Barcelona | Bayern München | 0-3 |
| 1 | 2021-09-14 | Dynamo Kyiv | Benfica | 0-0 |
| 2 | 2021-09-29 | Benfica | Barcelona | 3-0 |
| 2 | 2021-09-29 | Bayern München | Dynamo Kyiv | 5-0 |
| 3 | 2021-10-20 | Barcelona | Dynamo Kyiv | 1-0 |
| 3 | 2021-10-20 | Benfica | Bayern München | 0-4 |
| 4 | 2021-11-02 | Bayern München | Benfica | 5-2 |
| 4 | 2021-11-02 | Dynamo Kyiv | Barcelona | 0-1 |
| 5 | 2021-11-23 | Dynamo Kyiv | Bayern München | 1-2 |
| 5 | 2021-11-23 | Barcelona | Benfica | 0-0 |
| 6 | 2021-12-08 | Bayern München | Barcelona | 3-0 |
| 6 | 2021-12-08 | Benfica | Dynamo Kyiv | 2-0 |
| Team: | Matches | Wins | Draws | Losses | G-R | Points | |
| Bayern München | 6 | 6 | 0 | 0 | 22 | 3 | 18 |
| Benfica | 6 | 2 | 2 | 2 | 7 | 9 | 8 |
| Barcelona | 6 | 2 | 1 | 3 | 2 | 9 | 7 |
| Dynamo Kyiv | 6 | 0 | 1 | 5 | 1 | 11 | 1 |
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